MAGNESIUM
HYDROXIDE
CIMBAR:
MANUFACTURERS OF FLAME-RETARDANT FUNCTIONAL FILLERS
(Our MgOH products save lives)
Advantages
Filler
and Flame Retardant/Smoke Suppressant in one product
Environmentally
Acceptable
Halogen Free
Non-Corrosive
Reduces Smoke Density
Non-Volatile
Largely Inert
Thermally Stable up to 340º C
Economical
How Does
Magnesium Hydroxide Work?
By heating
above 340º C magnesium
hydroxide decomposes Endothermically emitting water according
to the reaction:
Mg (OH)
2 ------ MgO + H2O
- Endothermic
effect leads to temperature reduction
- Water
vapor as decomposition product forms a protective steam
layer in the gas phase
- Surface-active
Magnesium Oxide intermediates with absorption capability
to reduce smoke density
- Formation
of an inert Magnesium Oxide protective layer inhibits further
spread of flame
Compared
to Alumina Trihydrate
Reactivity
Magnesium
Hydroxide is much more reactive than Alumina Trihydrate
(ATH). Whereas ATH releases the available water over a
broad range (230º C to 430º C), Magnesium Hydroxide
releases the available water over a much narrower range
(330º C or 630º F to 430º C).
In simple terms this compares to spraying a fine mist of
water over a fire (ATH) as opposed to dousing the fire
with a full bucket of water (Magnesium Hydroxide). The
quick release of water enhances the flame retardant properties
of Magnesium Hydroxide.
Water
Release
Magnesium Hydroxide releases water at a higher
temperature than ATH. The higher temperature release is
at a more critical point that reduces the spread of the
flame.
Particle
Shape
Magnesium Hydroxide particles, if viewed under a
microscope, are plate-like versus the spherical particles
of ATH. These plate-like particles overlap one another
similar to fish scales or roofing shingles. Pound for pound
these plate-like particles offer much more exposed surface
area than spherical ATH particles. Therefore more particles
are directly exposed to the flame. Also, the plate-like
particles provide more strength, flexibility and reinforcement
in the finished product as opposed to spherical particles.
Particle
Integration
Magnesium Hydroxide is a natural mix of particles.
There is particle penetration and integration within Magnesium
Hydroxide rather than having ATH and calcium carbonate
particles mixed side by side. This allows a better distribution
of the fire retardant and smoke suppressant properties.
Stability
Magnesium
Hydroxide has stabilizing characteristics that tend to
neutralize acid and toxic smoke. ATH does not provide these
benefits.
Char
Ash
Magnesium Hydroxide during the burning reaction forms
a “Char-Ash” in front of the flame,
which suppresses the flame.
Compared
to Alumina Trihydrate
Physical properties such as viscosity
cure rate, stress strain and durometer, suggest that magnesium
hydroxide is virtually indistinguishable from ATH from a
filler performance standpoint.
It
has been established that combinations of ATH and Magnesium
Hydroxide produce less smoke than compounds filled with
the same total loading of either mineral alone.
Magnesium
Hydroxide, because of its acid scavenging properties, can
play a useful role in halogenated compounds by reducing
acid gas emissions.
By absorbing
some of the heat, magnesium hydroxide prevents or delays
ignition and retards combustion of polymeric materials.
Properties
of ATH and Magnesium Hydroxide |
|
ATH |
Magnesium
Hydroxide |
Molecular
Formula |
Al
(OH) 3 |
Mg
(OH) 2 |
Water
Content Loss on Ignition (LOI) |
34% |
31% |
Decomposition
Temperature |
Greater
than 230º C |
Greater
than 330º C |
Mohs
hardness |
2.5–3.5 |
2.0-3.0 |
Specific
Gravity |
2.42 |
2.36 |
pH |
9-10 |
10.5 |
Electrical
Conductivity |
|
us/cm
less than 350DIN 53208 |
Color |
White |
White |
Physical
Properties |
Powder |
Powder |
Refractive
Index |
1.57 |
1.58 |
Particle
Morphology |
Hexagonal
Platelet |
Hexagonal
Platelet |
We offer
standard dry ground products and a surface-treated product
to aid with dispersion and workability.
Other
products offer by Cimbar performance Minerals:
Calcium Carbonate
(Crescent Series)
Barium Sulfate (Cimbar EX, UF, XF, 325 & PC
to name a few)
Iron Oxide (4400 Series) Drilling Fluid
Barite (Bara 200 Series)
Pharmaceutical Barite (Bariscan
Series)
Bleached Industrial Barite (MitiWite Series
Sodium
Bentonite Clay
Calcium Bentonite Clay
All U.S.
Plant Locations:
Houston, Texas
Chatsworth, Georgia
Cartersville,
Georgia
Potosi, Missouri
Contact
Information:
14047 Industrial Road, Houston Texas 77015
Phone:
713-881-9466
Phone: 866-414-7504
Fax: 713-881-9471
www.cimbar.com
E-mail: mbrooks@cimbar.com
The Statements
Contained herein are based on data which is believed to
be reliable, and is offered in good faith to be applied
accordingly to the users own best judgment. We will not assume
responsibility for the accuracy of this data, or liability,
which may result from the use of these products. Likewise,
no patent liability is assumed for the use of these products
in any manner, which could or would infringe patent rights
of others.
®Barifine
and Bariace are registered trademarks of Sakai Chemical
Industry Company Ltd |